SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [(C(5)ME(5))RU(P2N2)](2)[ZNCL4]CENTER-DOT-2H(2)O

Authors
WONG WK CHEN Y WONG WT
Citation
Wk. Wong et al., SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [(C(5)ME(5))RU(P2N2)](2)[ZNCL4]CENTER-DOT-2H(2)O, Polyhedron, 15(9), 1996, pp. 1575-1577
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
9
Year of publication
1996
Pages
1575 - 1577
Database
ISI
SICI code
0277-5387(1996)15:9<1575:SAXCO[>2.0.ZU;2-D
Abstract
The interaction of [(C(5)Me(5))Ru(CH3CN)(3)](+) (generated in situ fro m the reaction of [(C(5)Me(5))RuCl2](n) with excess granular zinc in C H3CN) with one equivalent of s[o-(diphenylphosphino)benzylidene]ethyle nediamine (P2N2) in CH3CN at room temperature gave [(C(5)Me(5))Ru(P2N2 )](2)[ZnCl4]. 2H(2)O in good yield (80%). The compound has been fully characterized by analytical, spectroscopic and X-ray diffraction metho ds.