Ty. Brooke et al., A STUDY OF ABSORPTION FEATURES IN THE 3 MICRON SPECTRA OF MOLECULAR CLOUD SOURCES WITH H2O ICE BANDS, The Astrophysical journal, 459(1), 1996, pp. 209-215
New 3.3-3.6 mu m spectra were obtained of nine young stellar objects e
mbedded in molecular clouds. An absorption feature at similar to 3.47
mu m (2880 cm(-1)) with FWHM similar to 0.09 mu m (80 cm(-1)), first i
dentified by Allamandola et al. (1992), was definitively detected towa
rd seven objects, and marginally in the other two. The feature is bett
er correlated with H2O ice than with the silicate dust optical depth i
n the data obtained to date. Assuming the feature is due to a C-H stre
tch absorption, the abundance of the C-H bonds averaged along the line
s of sight is closely related to that of H2O ice. We interpret the cor
relation with H2O ice as indicating that the C-H bonds form together w
ith H2O ice on grain surfaces in the molecular clouds, though other fo
rmation mechanisms are not ruled out. A second absorption feature at 3
.25 mu m (3080 cm(-1)) was detected toward NGC 7538/IRS 1 and S140/IRS
1; this feature was first detected in spectra of Mon R2/IRS 3 (Sellgr
en, Smith, & Brooke 1994; Sellgren et al. 1995). There is as yet insuf
ficient data to tell whether this feature is better correlated with H2
O ice or silicates.