NMR AND OTHER STUDIES OF CAPRYLALDEHYDE ISONICOTINOYL HYDRAZONE AND ITS METAL-COMPLEXES

Authors
PURI V PATEL P AGARWALA BV
Citation
V. Puri et al., NMR AND OTHER STUDIES OF CAPRYLALDEHYDE ISONICOTINOYL HYDRAZONE AND ITS METAL-COMPLEXES, National Academy Science Letters, 18(9-10), 1995, pp. 167-171
Citations number
9
Categorie Soggetti
Multidisciplinary Sciences
Journal title
National Academy Science Letters → ACNP
ISSN journal
0250541X
Volume
18
Issue
9-10
Year of publication
1995
Pages
167 - 171
Database
ISI
SICI code
0250-541X(1995)18:9-10<167:NAOSOC>2.0.ZU;2-U
Abstract
A new hydrazone Schiff base ligand namely caprylaldehyde isonicotinoyl hydrazone (CINH) has been synthesised and characterised by H-1-NMR and electronic elemental analysis, IR, spectroscopy. The signal due to az omethinic proton H-C=N is observed at 8.50 ppm. Several bipositive met al ions were employed to form complexes. Thermal degradation of the co mplexes has been examined up to 1000 degrees C and the force constants of M-O and M-N bonds evaluated. The mode of complexation in enolic fo rm of the ligand in 4-coordinated complexes has been discussed.