EPOXIDATION AND CYCLOPROPANATION OF 2-SILYL-3-ALKENOLS - A STUDY OF 1,2-ASYMMETRIC INDUCTION

Authors
LANDAIS Y PARRARAPADO L
Citation
Y. Landais et L. Parrarapado, EPOXIDATION AND CYCLOPROPANATION OF 2-SILYL-3-ALKENOLS - A STUDY OF 1,2-ASYMMETRIC INDUCTION, Tetrahedron letters, 37(8), 1996, pp. 1205-1208
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
8
Year of publication
1996
Pages
1205 - 1208
Database
ISI
SICI code
0040-4039(1996)37:8<1205:EACO2->2.0.ZU;2-9
Abstract
Epoxidation and cyclopropanation of 2-silyl-3-alkenols have been shown to occur with high 1,2-stereocontrol through substrate directable rea ctions. Both syn and anti epoxides are thus available from E and Z-alk ylsilanes. This contrasts with the results usually observed for allyls ilanes lacking a coordinating group.