SYNTHESIS AND REACTIVITY OF NEW CHIRAL RHENIUM COMPLEXES OF UNSATURATED ALCOHOLS

Authors
LEGOUPY S CREVISY C GUILLEMIN JC GREE R
Citation
S. Legoupy et al., SYNTHESIS AND REACTIVITY OF NEW CHIRAL RHENIUM COMPLEXES OF UNSATURATED ALCOHOLS, Tetrahedron letters, 37(8), 1996, pp. 1225-1228
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
8
Year of publication
1996
Pages
1225 - 1228
Database
ISI
SICI code
0040-4039(1996)37:8<1225:SARONC>2.0.ZU;2-P
Abstract
New rhenium complexes of allylic, homoallylic and propargylic alcohols have been prepared. Starting from the allyl alcohol complex a multist ep sequence involving a chemoselective oxidation, a Wittig reaction an d a reduction leads to a conjugated dienone and dienol selectively com plexed at only one double bond.