POLYALKYLATION OF PRIMARY POLYOLS BY 1,4-ADDITION TO TERT-BUTYL ACRYLATE AND ACRYLONITRILE

Authors
DUPRAZ A GUY P DUPUY C
Citation
A. Dupraz et al., POLYALKYLATION OF PRIMARY POLYOLS BY 1,4-ADDITION TO TERT-BUTYL ACRYLATE AND ACRYLONITRILE, Tetrahedron letters, 37(8), 1996, pp. 1237-1240
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
8
Year of publication
1996
Pages
1237 - 1240
Database
ISI
SICI code
0040-4039(1996)37:8<1237:POPPB1>2.0.ZU;2-P
Abstract
The very hydrophilic primary polyols pentaerythritol (PE), 1,1,1-tris- (hydroxymethyl)ethane and tris(hydroxymethyl)aminomethane (TRIS), cam be polyetherified in satisfactory yield by 1,4-addition to tert-butyl acrylate using phase-transfer catalysis. Polycyanoethylation of these polyols can also be accomplished with acrylonitrile. Preliminary resul ts of chelation between some polyether-acids with samarium (III) are p resented.