AN IMPROVED AND GENERAL-METHOD FOR THE SYNTHESIS OF ALPHA,BETA-UNSATURATED OXIMES FROM PHOSPHINE OXIDE ALLENES

Authors
PALACIOS F APARICIO D DELOSSANTOS JM RODRIGUEZ E
Citation
F. Palacios et al., AN IMPROVED AND GENERAL-METHOD FOR THE SYNTHESIS OF ALPHA,BETA-UNSATURATED OXIMES FROM PHOSPHINE OXIDE ALLENES, Tetrahedron letters, 37(8), 1996, pp. 1289-1292
Citations number
39
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
8
Year of publication
1996
Pages
1289 - 1292
Database
ISI
SICI code
0040-4039(1996)37:8<1289:AIAGFT>2.0.ZU;2-W
Abstract
A simple and very efficient route to alpha beta-unsaturated oximes 1 h as been developed. These compounds are obtained through olefination re action of beta-oximo phosphine oxide derivatives 2, easily obtained by addition of hydroxylamine compounds to aIlenes 3.