KINETICS OF THE REACTION OF THE SULFATE RADICAL WITH THE OXALATE ANION

Authors
HUIE RE CLIFTON CL
Citation
Re. Huie et Cl. Clifton, KINETICS OF THE REACTION OF THE SULFATE RADICAL WITH THE OXALATE ANION, International journal of chemical kinetics, 28(3), 1996, pp. 195-199
Citations number
31
Categorie Soggetti
Chemistry Physical
Journal title
International journal of chemical kinetics → ACNP
ISSN journal
05388066
Volume
28
Issue
3
Year of publication
1996
Pages
195 - 199
Database
ISI
SICI code
0538-8066(1996)28:3<195:KOTROT>2.0.ZU;2-1
Abstract
The kinetics of the reaction of the sulfate radical, SO4-, with the ox alate anion, C2O42- was studied in aqueous solution and second-order r ate constants, corrected For the effects of ionic strength, derived. M easurements were carried out over the temperature range 24-60 degrees C resulting in the expression k(0) = 2.10 +/- 0.96 x 10(8) exp(-1080 /- 140/T) L mol(-1) s(-1). (C) 1996 John Wiley & Sons, Inc.