CHARGE-TRANSFER SALTS CONTAINING CYCLIC PERFLUORINATED ANIONS

Citation
Mw. Briscoe et al., CHARGE-TRANSFER SALTS CONTAINING CYCLIC PERFLUORINATED ANIONS, Journal of fluorine chemistry, 76(1), 1996, pp. 1-2
Citations number
3
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
00221139
Volume
76
Issue
1
Year of publication
1996
Pages
1 - 2
Database
ISI
SICI code
0022-1139(1996)76:1<1:CSCCPA>2.0.ZU;2-B
Abstract
Perfluorobicyclopentenyl (1a) and -butenyl (2a) react with decamethylf errocene (3), to give charge-transfer salts 4 and 5, respectively; per fluorohexakis (trifluoromethyl) cyclo-pentadiene (6) forms a salt (8) containing the C-5(CF3)(5) anion, Crystal structures of the salts 4 an d 5 have been determined; both contain centrosymmetric trans-diene rad ical anions.