Ds. Coombs et al., PORPHYROBLASTIC MANGANAXINITE METAPELAGITES WITH INCIPIENT GARNET IN PREHNITE-PUMPELLYITE FACIES, NEAR MEYERS PASS, TOULESSE TERRANE, NEW-ZEALAND, Journal of metamorphic geology, 14(2), 1996, pp. 125-142
Moderately manganiferous siliceous pelagites near Meyers Pass, Torless
e Terrane, South Canterbury, New Zealand, have been metamorphosed in t
he prehnite-pumpellyite facies. A conodont colour index measurement su
ggests T-max in the range 190-300 degrees C. Porphyroblastic manganaxi
nite, manganoan pumpellyite, manganoan chlorite and trace spessartine-
rich garnet and sphalerite have formed in an extremely fine-grained qu
artz-albite-berthierine-phengite-titanite groundmass. Porphyroblastic
manganaxinite semischists and schists are distinctive rocks in prehnit
e-pumpellyite to lower-grade greenschist and blueschist facies of New
Zealand and Japan. Mn in the manganoan pumpellyites substitutes for Ca
in W sites. Total Fe/(Fe + Mg) ratios in chlorite are dependent on ox
idation state, being less than or equal to 0.22 in red hematitic hemip
elagites, and greater than or equal to 0.61 in low-fO(2) grey metapela
gites. In the low-fO(2) metapelagites, manganoan berthierine with litt
le or no chlorite is inferred in the groundmass and iron-rich chlorite
occurs as porphyroblasts and veinlets, whereas in the red rocks, Mg-r
ich chlorite occurs both in groundmasses and veinlets. Variably high S
i in the manganoan chlorites correlates with evidence for contaminant
phases. The Mn content of chlorite contributing to garnet growth is de
pendent on metamorphic grade; incipient spessartine indicates a satura
tion value of 6-8% MnO in chlorite in low-fO(2) rocks at Meyers Pass.
Lower MnO contents are recorded for otherwise analogous rocks with inc
reasing metamorphic grade, but at a given grade coexisting chlorite an
d garnet are richer in Mn where fO(2) is high. Manganaxinite and manga
noan pumpellyite also contributed to reactions forming grossular-spess
artine solid solutions. Formation of garnet in siliceous pelagites is
dependent on both Mn and Ca content. The spessartine component increas
es with grade into the greenschist facies. Partial recrystallization o
f berthierine to chlorite and the growth of porphyroblastic patches of
other minerals was facilitated by brittle fracture and access of flui
ds to an otherwise impermeable matrix; to this extent the very low-gra
de metamorphism was episodic.