REACTION OF SODIUM AMALGAM WITH CARBENIUM IONS SPECIES STABILIZED BY 2 ADJACENT ORGANOMETALLIC MOIETIES

Authors
CAPON JF LEBERRECOSQUER N KERGOAT R
Citation
Jf. Capon et al., REACTION OF SODIUM AMALGAM WITH CARBENIUM IONS SPECIES STABILIZED BY 2 ADJACENT ORGANOMETALLIC MOIETIES, Journal of organometallic chemistry, 508(1-2), 1996, pp. 1-6
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
508
Issue
1-2
Year of publication
1996
Pages
1 - 6
Database
ISI
SICI code
0022-328X(1996)508:1-2<1:ROSAWC>2.0.ZU;2-T
Abstract
The ionic complexes Mo(2)(CO)(4){mu-eta(2):eta(3)-HC=C-C(H)(Fc)}][BF4] (1) and CO)(4)(mu-eta(2):eta(3)-HC=C-C(H)}(2)Fc][{BF4}(2)] (5) react with Na-Hg in toluene solution. The results are interpreted in terms o f a radical mechanism involving intramolecular and intermolecular coup ling reactions.