SYNTHESIS OF SECONDARY ALLENYLIDENE-MOLYBDENUM COMPLEXES WITH A FERROCENYL SUBSTITUENT FROM CARBENIUM IONS SPECIES STABILIZED BY 2 ORGANOMETALLIC MOIETIES

Authors
CAPON JF LEBERRECOSQUER N LEBLANC B KERGOAT R
Citation
Jf. Capon et al., SYNTHESIS OF SECONDARY ALLENYLIDENE-MOLYBDENUM COMPLEXES WITH A FERROCENYL SUBSTITUENT FROM CARBENIUM IONS SPECIES STABILIZED BY 2 ORGANOMETALLIC MOIETIES, Journal of organometallic chemistry, 508(1-2), 1996, pp. 31-37
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
508
Issue
1-2
Year of publication
1996
Pages
31 - 37
Database
ISI
SICI code
0022-328X(1996)508:1-2<31:SOSACW>2.0.ZU;2-E
Abstract
The monoallenylidene complex [Cp(2)Mo(2)(CO)(4){mu-sigma:eta(2)-C=C-C( Fc)(H)}] (5) and the diallenylidene complex Cp(2)Mo(2)(CO)(4)(mu-sigma :eta(2)-C=C=C(H))}(2)Fc] (6) have been obtained from the corresponding monocarbenium ion Mo(2)(CO)(4){mu-eta(2):eta(3)-HC=C-C(H)(Fc)}][BF4] (3) and the dicarbenium ion CO)(4)(mu-eta(2):eta(3)-HC=C-C(H)}(2)Fc][( BF4)(2)] (4) respectively, and their spectroscopic data are determined .