C. Dehnbostel et al., FINE-STRUCTURE TRANSITIONS IN METASTABLE NE-ASTERISK(P-3(0,2)) COLLIDING WITH H-2, HD, D-2, O-2, AND H2O AT THERMAL ENERGIES, The Journal of chemical physics, 104(9), 1996, pp. 3211-3216
The XUV photon emission following collision-induced fine-structure tra
nsitions Ne(P-3(0,2))+M --> Ne*(P-1,3(1))+M --> Ne(S-1)+M+hv(74 nm) h
as been measured for M=H-2, HD, D-2, O-2, and H2O in a beam-cell exper
iment. The metastable Ne velocity ranges from 500 to 1500 m/s. No emi
ssion was found for Ne(P-3(0))+M. An appropriate detector system enab
les the determination of absolute P-3(2) -->P-3(1) transition cross se
ctions. The hierarchy of the cross sections measured parallels that of
collision-induced P-2(1/2)-->P-2(3/2) transition cross sections in Rb
(5(2)P) and Cs(6(2)P) which have comparable fine-structure energy spli
ttings. (C) 1996 American Institute of Physics.