S. Stallinga et al., INFLUENCE OF SURFACE ELASTICITY ON THE DIRECTOR PROFILE OF NONTWISTEDNEMATIC-LIQUID-CRYSTAL CELLS, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics, 53(2), 1996, pp. 1701-1713
The Pergamenshchik theory [Phys. Rev. E 48, 1254 (1993)] and Faetti th
eory [Phys. Rev. E 49, 5332 (1994); 49, 4192 (1994)] of surface elasti
city in nematic liquid crystals are tested. Both theories give differe
nt predictions concerning the influence of the splay-bend surface elas
tic constant K-13 on the director profile of nontwisted liquid-crystal
cells. The influence of K-13 on the director profile of nontwisted li
quid-crystal cells is studied numerically within the framework of the
Pergamenshchik theory. The capacitance and optical retardation of thin
cells filled with the liquid crystal ZLI 4792 (E. Merck, Darmstadt, G
ermany) are measured as a function of the applied voltage. The surface
tilt as a function of the applied voltage is calculated from these da
ta and compared with numerically calculated curves. The model does not
give a complete account of the observed optical behavior. Best agreem
ent with the capacitive measurements is obtained with K-13 = 0. The ef
fect of K-13 is comparable in magnitude with the effect of variations
of the bulk liquid-crystal parameters within their experimental inaccu
racy.