Three separate experiments are described which use laser radiation to
probe the details of electron scattering processes from metal vapour t
argets. Results from superelastic scattering experiments from calcium
are presented. The experiments were carried out at incident energies o
f 25 . 7 and 45 eV referred to the ground state. Scattering amplitudes
derived from these experiments demonstrate that current theories are
inadequate. The coherence of the excitation process has been studied b
y measuring the total polarisation. It is shown that the excitation pr
ocess is coherent over the whole kinematic range. Preliminary results
from a study of superelastic electron scattering from lithium are disc
ussed where it is shown that a quantum electrodynamical model can be u
sed to describe the optical pumping process in Li-6 and Li-7. In addit
ion the first superelastic electron spectrum is presented for experime
nts on lithium. A stepwise excitation technique is described with whic
h cross sections for the electron impact excitation of the 3d(9)-4s(2)
D-2 state in copper can be measured. The experiments are complicated
by the presence of D states in the incident copper beam. The origin of
these D states is described as is a modification of the technique whi
ch leads to their removal.