ELECTRON-AFFINITY OF CO(CO)(2)NO MEASURED BY NEGATIVE-ION PHOTOELECTRON-SPECTROSCOPY

Authors
TURNER NJ MARTEL AA WALLER IM
Citation
Nj. Turner et al., ELECTRON-AFFINITY OF CO(CO)(2)NO MEASURED BY NEGATIVE-ION PHOTOELECTRON-SPECTROSCOPY, Journal of physical chemistry, 98(2), 1994, pp. 474-477
Citations number
44
Categorie Soggetti
Chemistry Physical
Journal title
Journal of physical chemistry → ACNP
ISSN journal
00223654
Volume
98
Issue
2
Year of publication
1994
Pages
474 - 477
Database
ISI
SICI code
0022-3654(1994)98:2<474:EOCMBN>2.0.ZU;2-Y
Abstract
In this work, we present the fixed-frequency (at 355 nm) negative-ion photoelectron spectrum of Co(CO)(2)NO-. Analysis of the spectrum yield s the electron affinity of Co(CO)(2)NO; EA[Co(CO)(2)NO] = 1.73 +/- 0.0 3 eV. The lack of extensive vibrational progressions in the spectrum i s consistent with the neutral species and the negative-ion having simi lar equilibrium geometries.