CYCLOADDITION OF METHYLAZIDE AND PHENYLAZ IDE WITH BETA-NITROSTYRENE AND HOMOLOGOUS NITROPROPENE

Authors
CAILLEUX P PIET JC BENHAOUA H CARRIE R
Citation
P. Cailleux et al., CYCLOADDITION OF METHYLAZIDE AND PHENYLAZ IDE WITH BETA-NITROSTYRENE AND HOMOLOGOUS NITROPROPENE, Bulletin des Societes chimiques belges, 105(1), 1996, pp. 45-51
Citations number
27
Categorie Soggetti
Chemistry
Journal title
Bulletin des Societes chimiques belges → ACNP
ISSN journal
00379646
Volume
105
Issue
1
Year of publication
1996
Pages
45 - 51
Database
ISI
SICI code
0037-9646(1996)105:1<45:COMAPI>2.0.ZU;2-B
Abstract
Phenylazide and emthylazide reacts with title olefines and gives two i someric triazoles without nitro group, and 4-nitro-1,2,3 triazole. The isomerisation of starting alkenes explains the formation of isomeric triazoles. Oxydation of amino-nitro-diazocompounds in equilibrium with 1,2,3 triazolines leads to 4-nitro-1,2,3 triazoles.