MIMICS OF L-RHAMNOSE - ANOMERIC SPIROHYDANTOINS AND DIKETOPIPERAZINES- APPROACHES TO NOVEL N-LINKED GLYCOPEPTIDES OF RHAMNOFURANOSE

Authors
ESTEVEZ JC SMITH MD LANE AL CROOK S WATKIN DJ BESRA GS BRENNAN PJ NASH RJ FLEET GWJ
Citation
Jc. Estevez et al., MIMICS OF L-RHAMNOSE - ANOMERIC SPIROHYDANTOINS AND DIKETOPIPERAZINES- APPROACHES TO NOVEL N-LINKED GLYCOPEPTIDES OF RHAMNOFURANOSE, Tetrahedron : asymmetry, 7(2), 1996, pp. 387-390
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
7
Issue
2
Year of publication
1996
Pages
387 - 390
Database
ISI
SICI code
0957-4166(1996)7:2<387:MOL-AS>2.0.ZU;2-7
Abstract
An alpha-azidocarboxylate of a tetrahydrofuran derived from L-rhamnose may be used as a divergent intermediate for a wide range of mimics of L-rhamnofuranose, which contain a constituent alpha-amino acid moiety at the anomeric position, and include anomeric spiroderivatives such as the rhamnose analogue of hydantocidin; such materials may be helpfu l in elucidating the biosynthesis of the cells walls of mycobacteria.