ENANTIOPURE ATROPISOMERIC PHOSPHOROTHIOATES AND PHOSPHOROTHIOAMIDATES

Authors
DELOGU G FABBRI D DETTORI MA
Citation
G. Delogu et al., ENANTIOPURE ATROPISOMERIC PHOSPHOROTHIOATES AND PHOSPHOROTHIOAMIDATES, Tetrahedron : asymmetry, 7(2), 1996, pp. 413-416
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
7
Issue
2
Year of publication
1996
Pages
413 - 416
Database
ISI
SICI code
0957-4166(1996)7:2<413:EAPAP>2.0.ZU;2-N
Abstract
The straightforward preparation and resolution of phosphorothioates an d phosphorothioamidates from 1,1'-biphenyl-2,2'-diol 1 and 1,1'-binaph thalene-2,2'-diol 2 are described. Basic alcoholysis of phosphorothioa midate of 1,1'-binaphthalene-2,2'-diol 6b and 6c is highly stereoselec tive and gives only one diastereomer.