THE ROVIBRATIONAL INTENSITIES OF THE (40(0)1)[-(00(0)0) PENTAD ABSORPTION-BANDS OF (CO2)-C-12-O-16 BETWEEN 7284 AND 7921 CM(-1)

Authors
GIVER LP CHACKERIAN C SPENCER MN BROWN LR WATTSON RB
Citation
Lp. Giver et al., THE ROVIBRATIONAL INTENSITIES OF THE (40(0)1)[-(00(0)0) PENTAD ABSORPTION-BANDS OF (CO2)-C-12-O-16 BETWEEN 7284 AND 7921 CM(-1), Journal of molecular spectroscopy, 175(1), 1996, pp. 104-111
Citations number
22
Categorie Soggetti
Spectroscopy,"Physics, Atomic, Molecular & Chemical
Journal title
Journal of molecular spectroscopy → ACNP
ISSN journal
00222852
Volume
175
Issue
1
Year of publication
1996
Pages
104 - 111
Database
ISI
SICI code
0022-2852(1996)175:1<104:TRIOT(>2.0.ZU;2-E
Abstract
Absolute line intensities and Herman-Wallis type intensity parameters of (CO2)-C-12-O-16, experimentally measured for the first time for the (40 degrees 1)(IV) <-- (00 degrees 0) band at 7460 cm(-1) and the (40 degrees 1)(l) <-- (00 degrees 0) band at 7921 cm(-1). The rotationles s band strengths at 296 K are respectively s(vib)(o)[IV] = 0.0429(6) x 10(-22) Cm-1/(molecule/Cm-2) S-vib(o)[I] = 0.00189(6) X 10(-22) cm(-1 )/(molecule/cm(2)). In addition, previous measurements on the (40 degr ees 1)(II) <-- (00 degrees 0) and (40 degrees 1)(III) <-- (00 degrees 0) bands have been reanalyzed to be consistent with definitions of Her man-Wallis parameters currently in use. (C) 1996 Academic Press, Inc.