Lb. Zhang et al., FABRICATION OF A POROUS SILICON DIODE POSSESSING DISTINCT RED AND ORANGE ELECTROLUMINESCENT REGIONS, Journal of the Electrochemical Society, 143(2), 1996, pp. 42-44
Porous silicon light emitting diodes with distinct red and orange elec
troluminescent (EL) regions have been fabricated. Red luminescence is
obtained by sonication of the as-formed orange-emitting porous silicon
layers. While the red luminescence in the as-formed substrate is unst
able in air or under irradiation, deposition of a thin layer of poly(9
-vinyl cabazole) (PVK) by spin-coating effectively circumvents the oxi
dation process. The overall EL efficiency of the red and orange region
s can be improved by depositing a thin film of a 1:1 (w/w) mixture of
PVK and PBD [2-(4-biphenylyl)-5-(4-tert-butyl-phenyl)-1, 3, 4-oxadiazo
le] on the porous Si surface.