LIQUID-PHASE METHANOL SYNTHESIS - MODELING OF A MONOLITHIC REACTOR

Citation
A. Cybulski et al., LIQUID-PHASE METHANOL SYNTHESIS - MODELING OF A MONOLITHIC REACTOR, Chemical Engineering Science, 48(20), 1993, pp. 3463-3478
Citations number
35
Categorie Soggetti
Engineering, Chemical
ISSN journal
00092509
Volume
48
Issue
20
Year of publication
1993
Pages
3463 - 3478
Database
ISI
SICI code
0009-2509(1993)48:20<3463:LMS-MO>2.0.ZU;2-4
Abstract
A mathematical model of a monolithic reactor for liquid-phase methanol synthesis is developed. The performance of a commercial-scale monolit hic reactor is simulated. The influence of various design parameters f or different solvents and process conditions is studied. Over the rang e of process conditions considered, it was found that the mass transfe r is sufficiently fast to allow the process to be operated essentially in the kinetic regime. The numerical results are compared with litera ture data on slurry columns, autoclaves and trickle-bed reactors. The performance of the monolithic reactor was found to be commensurable wi th these reactors. In view of some of the unique advantages of the mon olithic reactor it can be a viable alternative to the conventional met hanol reactors.