COMPARISON OF DIFFERENT 6-TERT-BUTYLDIMETHYL-SILYLATED CYCLODEXTRINS AS CHIRAL STATIONARY PHASES IN GC

Authors
MAAS B DIETRICH A MOSANDL A
Citation
B. Maas et al., COMPARISON OF DIFFERENT 6-TERT-BUTYLDIMETHYL-SILYLATED CYCLODEXTRINS AS CHIRAL STATIONARY PHASES IN GC, The Journal of microcolumn separations, 8(1), 1996, pp. 47-56
Citations number
18
Categorie Soggetti
Chemistry Analytical
Journal title
The Journal of microcolumn separations → ACNP
ISSN journal
10407685
Volume
8
Issue
1
Year of publication
1996
Pages
47 - 56
Database
ISI
SICI code
1040-7685(1996)8:1<47:COD6CA>2.0.ZU;2-1
Abstract
Separation factors and thermodynamic data for the separation of variou s chiral analytes on different 6-TBDMS-derivatized gamma(beta)-cyclode xtrin-phases were collected and discussed. Modifying the alkyl chain l ength of the substituents in position 2, and 3 of the cyclodextrin mol ecule or changing from beta to gamma-CD affects the separation propert ies extremely, whereas changing the chain length of acyl groups in pos ition 2 and 3 hardly influences enantioselectivity. (C) 1996 John Wile y & Sons, Inc.