P. Mohn et al., THE FCC-BCC STRUCTURAL TRANSITION .2. A MEAN-FIELD MODEL FOR FINITE-TEMPERATURE EFFECTS, Journal of physics. Condensed matter, 8(7), 1996, pp. 817-827
We present a model for temperature induced martensitic phase transitio
ns where the excitations leading to the phase instability are local fl
uctuations of the respective order parameter which describes the displ
acement of a single atom or an atomic plane when transforming structur
e A into structure B. The fluctuations of the order parameter are heat
ed in the framework of a Landau-Ginzburg model and allow us to describ
e the temperature induced first-order phase transition as being driven
by strain fluctuations (caused by anharmonicities) rather than by pho
non softening. In some materials this phenomenological mean field trea
tment represents a possible model for martensitic phase transitions.