M. Cantoni et al., CHARACTERIZATION OF SUPERCONDUCTING HG-BA-CA-CU-OXIDES - STRUCTURAL AND PHYSICAL ASPECTS, Physica. C, Superconductivity, 215(1-2), 1993, pp. 11-18
Some of the recently discovered high-T(c) superconducting phases of Hg
-Ba-Ca-Cu-oxides have been investigated and characterised by analytica
l and high-resolution transmission electron microscopy. The highest me
asured critical temperature T(c) of 133.5 K can be assigned to the Hg1
Ba2Ca2Cu3O8+x phase (Hg-1223). Besides Hg-1212 and Hg-1223 phases, dif
ferent perfectly-ordered polytypes with large c-axes up to 19 nm consi
sting of different stackings of Hg-1212 and Hg-1223 have been observed
. The investigated oxide materials contain also several different stac
king defects consisting of intercalated layers of the related Hg-1234
and Hg-1245 structures.