Plw. Tregennapiggott et al., CALCULATION OF THE AVOIDED LEVEL-CROSSING MUON SPIN-RESONANCE RESPONSE FOR VARIOUS STOCHASTIC MOTIONS USING MONTE-CARLO METHODS, Chemical physics, 203(3), 1996, pp. 317-337
Spectral simulations of the dynamic avoided level-crossing muon spin r
esonance response, calculated using Monte Carlo methods, are presented
, This work is exclusively concerned with the band associated with the
Delta M = 1 transition, the form of which is found to be highly depen
dent upon the nature of the dynamic behaviour of the radical. Various
types of stochastic motion are considered, It is shown that spherical
averaging of the muon anisotropy instigates a broadening of the resona
nce and ultimately, the loss of any meaningful intensity. Any motion w
hich gives rise to residual anisotropy will be manifested by residual
intensity at the central band position, Spectral simulations are compa
red with previous simulations, calculated using the stochastic Liouvil
le formalism, and related to experimental data.