This Letter presents the first observation of [Si x] emission in a cel
estial object other than the solar corona. The detected line at 1.430
mu m is present in the spectra of both NGC 1068 and NGC 7469. The ioni
zation potential of Si x is 401.4 eV, which makes this one of the high
est ionization energy lines observed in active galactic nuclei. The li
ne falls in a region of high telluric absorption that requires a fortu
itous combination of redshift and abnormally dry observing conditions
to observe.