Fb. Rasmussen et al., THE NITROGEN-PAIR OXYGEN DEFECT IN SILICON, Materials science & engineering. B, Solid-state materials for advanced technology, 36(1-3), 1996, pp. 91-95
The nitrogen-pair oxygen defect in silicon has been studied by infrare
d absorption spectroscopy on samples implanted with various combinatio
ns of N-14, N-15, O-16 and O-17. The measurements give direct evidence
for the involvement of nitrogen and oxygen in the defect and show tha
t the impurity atoms comprising the defect are only weakly coupled. Ab
initio cluster calculation on several models of the nitrogen-pair oxy
gen defect have been performed and are compared with experiment. Based
on these investigations a model consisting of a bridging oxygen atom
adjacent to the nitrogen pair is suggested.