Ia. Buyanova et al., PHOTOLUMINESCENCE CHARACTERIZATION OF SF6-O-2 PLASMA-ETCHING OF SILICON, Materials science & engineering. B, Solid-state materials for advanced technology, 36(1-3), 1996, pp. 100-103
We report on photoluminescence studies of defect formation and of subs
equent annealing in silicon after SF6-O-2 plasma treatment. Substantia
l damage of the near surface layer, caused by ion bombardment of the s
ilicon surface, is observed, in spite of the high etch rate of SF6-O-2
plasma. The defects induced give rise to a broad PL band in the 0.70-
1.00 eV spectral range and sharp C and G lines. The mechanisms of defe
ct formation and the role of oxygen contamination during SF6-O-2 react
ive-ion etching in these processes are analyzed.