PREPARATION AND REACTIONS OF SODIUM TELLU RIDE, NA2TE - CRYSTAL-STRUCTURE OF [NA(CH3OH)(3)]2TE2

Authors
THIELE KH STEINICKE A DUMICHEN U NEUMULLER B
Citation
Kh. Thiele et al., PREPARATION AND REACTIONS OF SODIUM TELLU RIDE, NA2TE - CRYSTAL-STRUCTURE OF [NA(CH3OH)(3)]2TE2, Zeitschrift fur anorganische und allgemeine Chemie, 622(2), 1996, pp. 231-234
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
622
Issue
2
Year of publication
1996
Pages
231 - 234
Database
ISI
SICI code
0044-2313(1996)622:2<231:PAROST>2.0.ZU;2-L
Abstract
Sodium telluride, Na2Te 1, is easily obtained by reaction of sodium wi th hexagonal tellurium in 1,2-dimethoxy-ethane in the presence of cata lytic amounts of naphthalene. Upon exposure to oxygen 1 reacts with me thanol forming [Na(CH3OH)(3)]Te-2(2) 2, which crystal structure was de termined. Compound 1, prepared in situ, can be conveniently converted into dialkyl tellurides, R(2)Te (R = C2H5, i-C3H7, CH2 = CH-CH2 3).