Y. Sugano et Ja. Katzenellenbogen, SYNTHESIS OF TETRADENTATE BISAMINO-BISTHIOL COMPLEXES OF OXORHENIUM(V) AS STRUCTURAL MIMICS OF STEROIDS, Bioorganic & medicinal chemistry letters, 6(4), 1996, pp. 361-366
Two tetradentate chelate systems have been synthesized in order to pre
pare metal complexes with oxorhenium(V) whose structures will mimic th
at of steroids. The chelate system with amide/amine/thioether/thiol do
nor sites failed to give a stable complex, but the corresponding diami
ne chelate gave a stable complex.