The paper presents a new physical approach to modelling of positive le
ader inception and breakdown of phase-to-phase insulation in air, expo
sed to critical switching impulses of synchronized peaks and opposite
polarity. The work constitutes a generalization of a recently publishe
d model dealing with phase-to-ground insulation and covers both conduc
tor-conductor and horizontal rod-rod configurations. The influence of
interphase separation, conductor height above ground, conductor radius
and relative amplitude of the negative impulse on critical insulation
strength is systematically investigated. A novel application of the m
odel is a physically based prediction of air density effects on phase-
to-phase leader inception and breakdown. The model findings are extens
ively compared with experimental results.