Novel aromatic polyesters have been synthesized by solution condensati
on reactions between hydroquinone and 3,4-disubstituted 2,5-thiophened
icarbonyl chlorides. The introduction of phenyl substituents in these
poly(p-phenylene 3,4-disubstituted 2,5-thiophendicarboxylate)s did not
enhance the fusibility nor the solubility of the resulting material w
hen compared to the unsubstituted parent polyester. The presence of et
hyl groups led to the formation of an insoluble semicrystalline aromat
ic polyester with a melting transition at 304 degrees C. Poly(p-phenyl
ene 3-methyl-4-propyl-2,5-thiophenedicarboxylate) was found to be solu
ble in chloroform and exhibited a melting transition at 242 degrees C.
All these polyesters are stable up to 350-400 degrees C. However, in
contrast to the unsubstituted parent polymer, all these aromatic polye
sters did not show any evidence of liquid crystallinity in the melt. O
n the basis of theoretical calculations, this behaviour can be related
to the ca. 143 degrees core angle of 3,4-disubstituted thiophenes.