STOPPED-FLOW KINETIC INVESTIGATION OF THE OXIDATION OF ASCORBIC-ACID BY IRON(III)BENZOHYDROXAMIC ACID

Citation
S. Lakshmi et al., STOPPED-FLOW KINETIC INVESTIGATION OF THE OXIDATION OF ASCORBIC-ACID BY IRON(III)BENZOHYDROXAMIC ACID, Journal of inorganic biochemistry, 61(3), 1996, pp. 155-163
Citations number
16
Categorie Soggetti
Biology,"Chemistry Inorganic & Nuclear
ISSN journal
01620134
Volume
61
Issue
3
Year of publication
1996
Pages
155 - 163
Database
ISI
SICI code
0162-0134(1996)61:3<155:SKIOTO>2.0.ZU;2-T
Abstract
The fast oxidation of ascorbic acid by Fe(III)benzohydroxamic acid com plex [Fe(BHA)(3)] has been investigated by the stopped-flow technique in aqueous ethanol medium at three pH values (4.6, 7.0, and 9.0). The reaction exhibits a first-order dependence of rate each on [ascorbic a cid] and [Fe(BHA)(3)], obeying Michaelis-Menton kinetics. The rate of the reaction was found to be pH-dependent.