ORGANOPHOSPHORIC COMPOUNDS WITH BETA-CYAN ETHYL-TYPE STRUCTURAL ELEMENTS .3. BETA-(DIALCOXYPHOSPHINYL) PROPIONITRILE SYNTHESIS

Authors
PETROV P VLAD FI MURESAN S VALCEANU R
Citation
P. Petrov et al., ORGANOPHOSPHORIC COMPOUNDS WITH BETA-CYAN ETHYL-TYPE STRUCTURAL ELEMENTS .3. BETA-(DIALCOXYPHOSPHINYL) PROPIONITRILE SYNTHESIS, Revista de chimie, 46(12), 1995, pp. 1065-1069
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Revista de chimie → ACNP
ISSN journal
00347752
Volume
46
Issue
12
Year of publication
1995
Pages
1065 - 1069
Database
ISI
SICI code
0034-7752(1995)46:12<1065:OCWBES>2.0.ZU;2-A
Abstract
This paper presents a new method for producing some dialkylphosphonate s with beta-cyanoethyl traces, based on the nucleophile addition in th e sodium methoxide basic catalysis of dialkylphosphite to acrylonitril e. Based on the results thus got, the possibility of nitrile group par tial hydrolysis with formic acid, in the presence of hydrochloric acid , without, affecting the phosphate ester group, was demonstrated.