DIELECTRIC-PROPERTIES OF CARBOXYMETHYLATED ISONONYLPHENOL ETHOXYLATES

Citation
Tm. Usacheva et al., DIELECTRIC-PROPERTIES OF CARBOXYMETHYLATED ISONONYLPHENOL ETHOXYLATES, Colloid journal of the Russian Academy of Sciences, 58(1), 1996, pp. 91-95
Citations number
19
Categorie Soggetti
Chemistry Physical
ISSN journal
1061933X
Volume
58
Issue
1
Year of publication
1996
Pages
91 - 95
Database
ISI
SICI code
1061-933X(1996)58:1<91:DOCIE>2.0.ZU;2-R
Abstract
Dielectric properties of carboxymethylates with various degrees of eth oxylation and carboxymethylation were studied at the frequency of 1 MH z in the temperature range 293 - 363 K. It was shown that, as the numb er of ethylene oxide groups per Na+ ion increases, the permittivity of carboxymethylates decreases and the dielectric dispersion shifts towa rd lower frequencies. Such effects may be caused by the increasing sol vating ability of the oxyethylene chain with respect to Na+ ions, as t he degree of ethoxylation rises.