FTIR STUDY OF CARBON-MONOXIDE OXIDATION AND SCRAMBLING AT ROOM-TEMPERATURE OVER GOLD SUPPORTED ON ZNO AND TIO2 .2.

An FTIR and quadrupole mass spectroscopic study of CO adsorption and o xidation with O-16(2) and O-18(2) is presented together with coadsorpt ion experiments of CO and water on gold supported on ZnO and TiO2. The experimental results are closely related to those presented in the pa rallel paper on copper catalysts supported on the same oxides. The mos t important points are as follows: (i) CO is found to be activated on the metallic particles on two kinds of sites, the normal terrace sites and sites at the borderline of the particles; (ii) there is evidence that on the examined samples there are metallic sites which are able t o adsorb both oxygen and carbon monoxide molecules at the same time; ( iii) carbon dioxide and carbonate-like species are formed; the asymmet ric stretching frequencies of CO2, the quadrupole mass spectroscopic a nalysis, and the IR spectra analysis reveal that with O-18(2), differe nt isotopic molecular CO2 is formed while the carbonate-like species h ave the same frequencies of those produced in O-16(2); (iv) there are two independent pathways for CO oxidation, a rapid direct oxidation of CO at the surface of the metallic particles and a slow induced oxidat ion with the surface lattice oxygen species of the supports; (v) evide nce is found that CO-H2O coadsorption experiments produce atomic hydro gen on Au/ZnO, not on Au/TiO2.