Lf. Song et M. Elimelech, CALCULATION OF PARTICLE DEPOSITION RATE UNDER UNFAVORABLE PARTICLE SURFACE INTERACTIONS, Journal of the Chemical Society. Faraday transactions, 89(18), 1993, pp. 3443-3452
Citations number
40
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
When repulsive colloidal interactions are involved, calculating the ra
te of particle deposition becomes particularly difficult. To overcome
the difficulty, a new (constant migration flux) boundary condition and
a sophisticated numerical procedure are introduced. With these proced
ures, smooth solutions of the equation are obtained for the entire dom
ain, including the region beyond the energy barrier adjacent to the co
llector surface. Numerical calculations demonstrate that the dependenc
e of particle deposition rate on flow velocity is quite different from
that reported previously. The difficulty of using the 'perfect-sink'
boundary condition in numerical solutions and the inadequacy of previo
us numerical methods are discussed.