THE RICH CHEMISTRY OF FULVALENE YLIDES - A DICHOTOMY IN PHOSPHONIUM SALT YLIDE HYDROLYSIS AND THE DEVELOPMENT OF A NEW SYNTHESIS OF AZULENES

Authors
GILHEANY DG KELLY PG MITCHELL CA WALKER BJ MALONE JF BLANEY J WILSON R
Citation
Dg. Gilheany et al., THE RICH CHEMISTRY OF FULVALENE YLIDES - A DICHOTOMY IN PHOSPHONIUM SALT YLIDE HYDROLYSIS AND THE DEVELOPMENT OF A NEW SYNTHESIS OF AZULENES, Phosphorus, sulfur and silicon and the related elements, 75(1-4), 1993, pp. 11-14
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
75
Issue
1-4
Year of publication
1993
Pages
11 - 14
Database
ISI
SICI code
1042-6507(1993)75:1-4<11:TRCOFY>2.0.ZU;2-D
Abstract
A series of fulvalene ylides was synthesised. Only weak aromatic effec ts were found across the ylide bond. Their chemistry includes the firs t example of a dichotomy in phosphonium salt/ylide hydrolysis, interes ting dynamic nmrs of the adducts with dimethyl acetylenedicarboxylate and a new synthesis of azulenes.