SOLUTION DYNAMICS OF PHOSPHONATE ESTER HYDROLYSIS

Authors
KOVACH IM
Citation
Im. Kovach, SOLUTION DYNAMICS OF PHOSPHONATE ESTER HYDROLYSIS, Phosphorus, sulfur and silicon and the related elements, 75(1-4), 1993, pp. 131-134
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
75
Issue
1-4
Year of publication
1993
Pages
131 - 134
Database
ISI
SICI code
1042-6507(1993)75:1-4<131:SDOPEH>2.0.ZU;2-H
Abstract
The character of buffer-catalyzed hydrolysis of four phosphonates, bis -(4-nitrophenyl) methylphosphonate (NMN), 4-nitrophenyl 2-propyl methy lphosphonate (IMN), 2-(3,3-dimethyl)butyl methylphosphonofluoridate (s oman), and 4-nitrophenyl 4-methylphenacyl methylphosphonate (MPMN), wa s investigated. The latter hydrolyzes by an intramolecular nucleophili c mechanism. The transition state for each reaction is discussed.