1,3-DIMETHYL-1,3,2-DIAZAPHOSPHOLIDINES-2-ONES - UNANTICIPATED PRECURSORS OF (Z) ACRILYC ACID-ESTERS

Authors
PATOIS C SAVIGNAC P
Citation
C. Patois et P. Savignac, 1,3-DIMETHYL-1,3,2-DIAZAPHOSPHOLIDINES-2-ONES - UNANTICIPATED PRECURSORS OF (Z) ACRILYC ACID-ESTERS, Phosphorus, sulfur and silicon and the related elements, 75(1-4), 1993, pp. 143-146
Citations number
4
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
75
Issue
1-4
Year of publication
1993
Pages
143 - 146
Database
ISI
SICI code
1042-6507(1993)75:1-4<143:1-UP>2.0.ZU;2-T
Abstract
The title compounds allow the Wittig-Homer synthesis of acrylic acid e sters with Z:E ratios superior to 90:10 (THF, Li+). The selectivity is mainly controlled by the concentration and the temperature of the rea ction medium.