TRANSANULAR EQUILIBRIUM BETWEEN BICYCLOPHOSPHORANES AND PHOSPHANES

Authors
LAMANDE L MUNOZ A
Citation
L. Lamande et A. Munoz, TRANSANULAR EQUILIBRIUM BETWEEN BICYCLOPHOSPHORANES AND PHOSPHANES, Phosphorus, sulfur and silicon and the related elements, 75(1-4), 1993, pp. 241-244
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
75
Issue
1-4
Year of publication
1993
Pages
241 - 244
Database
ISI
SICI code
1042-6507(1993)75:1-4<241:TEBBAP>2.0.ZU;2-7
Abstract
The compound prepared from the reaction of phenyldichlorophosphine on 5-bromo-N(carboxymethyl)anthranilic acid, in presence of triethylamine , exhibits an original equilibrium connecting a bicyclophosphorane and its isomers bearing a tricoordinate phosphorus atom. With 2,2'-iminod ibenzoic acid, only phosphanes are obtained.