FACILE DEPROTECTION OF TRIMETHYLSILYL ETHERS WITH MODIFIED, BOROHYDRIDE AGENTS - 1-BENZYL-4-AZA-1-AZONIABICYCLO[2.2.2]OCTANE TETRAHYDROBORATE (BAAOTB) VERSUS TETRABUTYLAMMONIUM TETRAHYDROBORATE(TBATB)

Authors
FIROUZABADI H AFSHARIFAR GR
Citation
H. Firouzabadi et Gr. Afsharifar, FACILE DEPROTECTION OF TRIMETHYLSILYL ETHERS WITH MODIFIED, BOROHYDRIDE AGENTS - 1-BENZYL-4-AZA-1-AZONIABICYCLO[2.2.2]OCTANE TETRAHYDROBORATE (BAAOTB) VERSUS TETRABUTYLAMMONIUM TETRAHYDROBORATE(TBATB), Synthetic communications, 26(6), 1996, pp. 1065-1073
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
26
Issue
6
Year of publication
1996
Pages
1065 - 1073
Database
ISI
SICI code
0039-7911(1996)26:6<1065:FDOTEW>2.0.ZU;2-U
Abstract
Deprotection of structurally different trimethylsilyl ethers with the modified borohydride agents BAAOTB and TBATB to their corresponding al cohols in reflexing t-BuOH is described. Both BAAOTB and TBATB are eff icient reagents for this purpose. BAAOTB seems to be more selective th an TBATB.