PREPARATION AND CHARACTERIZATION OF O,O'-DIALKYLDITHIOPHOSPHATE COMPLEXES OF METHYLPLATINUM(II)

Authors
JAIN VK CHAUDHURY S
Citation
Vk. Jain et S. Chaudhury, PREPARATION AND CHARACTERIZATION OF O,O'-DIALKYLDITHIOPHOSPHATE COMPLEXES OF METHYLPLATINUM(II), Polyhedron, 15(10), 1996, pp. 1685-1689
Citations number
37
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
10
Year of publication
1996
Pages
1685 - 1689
Database
ISI
SICI code
0277-5387(1996)15:10<1685:PACOOC>2.0.ZU;2-C
Abstract
The reaction of [PtMe(X)(COD)] (X = Cl, I) with 1 mole equivalent of N H4 SSP(OR')(2) gave [{Pt(Me)SSP(OR')(2)}2COD] (R' = Et or Pr-i). The l atter complexes on treatment with tertiary phosphines afforded [Pt(Me) {SSP(OR')(2)}(PR(3))](R = 4-MeC(6)H(4),2-MeC(6)H(4) or (2,4,6-MeO)(3)C 6H2). All the complexes were characterized by elemental analysis, and NMR data.