A NOVEL TETRANUCLEAR IRON(III) COMPLEX HAVING L-ALANINE BRIDGES AND AN UNPRECEDENTED (FE-4(O2H)) CORE

Authors
YANO S INAGAKI T YAMADA Y KATO M YAMASAKI M SAKAI K TSUBOMURA T SATO M MORI W YAMAGUCHI K KINOSHITA I
Citation
S. Yano et al., A NOVEL TETRANUCLEAR IRON(III) COMPLEX HAVING L-ALANINE BRIDGES AND AN UNPRECEDENTED (FE-4(O2H)) CORE, Chemistry Letters, (1), 1996, pp. 61-62
Citations number
34
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
1
Year of publication
1996
Pages
61 - 62
Database
ISI
SICI code
0366-7022(1996):1<61:ANTICH>2.0.ZU;2-P
Abstract
The reaction of L-alanine (L-ala) with Fe(NO3)(2) . 9H(2)O in the pres ence of H(5)dhpta 1,3-diamino-2-hydroxypropane-N,N,N',N'-tetraacetic a cid) and base (NaOH) affords the novel tetranuclear complex Na[Fe-4(dh pta)(2)(O)(OH)(L-ala)(2)]. 6H(2)O having L-alaninato bridges and an (F e-4(O2H))(9+) core whose crystal structure and magnetic properties wer e determined.