J. Luengo et Nv. Joshi, COMPOSITION DEPENDENCE OF THE ENERGY-GAP OF ZNXMN1-XIN2SE4 AND OPTICAL-ABSORPTION SPECTROSCOPY, Materials letters, 26(1-2), 1996, pp. 47-50
Composition dependence of the band gap of ZnxMn1-xIn2Se4 alloys has be
en studied at 300 K and 77 K for the first time. It was found that for
smaller concentrations of Mn the band gap varies linearly with compos
ition and for higher concentrations it shows quadratic dependence. The
same trend of dependence was observed for both temperatures. Absorpti
on spectra do reveal the structure located on the higher energy side o
f the main band gap which has been interpreted on the basis of valence
band structure, like, crystal field and spin-orbit interactions.