The food industry produces an increasing variety of formulated foods.
Processed food systems usually contain proteins and polysaccharides pe
rforming both nutritional and structural functions. Interactions betwe
en these macromolecular substances may result both in their thermodyna
mic incompatibility and in complexing, thereby affecting the physico-c
hemical properties and structure of many foods. Elucidation of these i
nteractions is of particular importance for understanding synergistic
and antagonistic effects of food additives. This paper reviews the the
rmodynamic origin of food hydrocolloid functionality.