Cf. Delale et al., THEORY OF EMBEDDED SHOCK FORMATION IN RAREFACTION WAVES BY HOMOGENEOUS CONDENSATION, European journal of mechanics. B, Fluids, 15(1), 1996, pp. 81-102
A theory of embedded shock formation by homogeneous condensation in th
e centered rarefaction wave of a shock tube is presented. The necessar
y and sufficient conditions for the existence of such embedded shock w
aves are exhibited in a parabolic approximation to the family of inter
secting characteristics. In particular the coordinates of the embedded
shock origin are derived explicitly by the construction of the envelo
pe of the family. Predictions of the theory, including an estimate for
the average embedded shock speed, are substantiated by comparison of
the results obtained employing the classical nucleation theory and Her
tz-Knudsen droplet growth law for the condensation model with those of
typical experiments showing visualized shocks formed by homogeneous c
ondensation during the expansion of water vapor in nitrogen (or air).