ROOM-TEMPERATURE LITHIUM REDUCTION OF LA2MO4+DELTA (M = CU, NI)

Authors
RIAL C AMADOR U VAREZ A MORAN E ALARIOFRANCO MA GONZALEZ A PINGARRON JM
Citation
C. Rial et al., ROOM-TEMPERATURE LITHIUM REDUCTION OF LA2MO4+DELTA (M = CU, NI), Solid state ionics, 63-5, 1993, pp. 907-914
Citations number
12
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical
Journal title
Solid state ionics → ACNP
ISSN journal
01672738
Volume
63-5
Year of publication
1993
Pages
907 - 914
Database
ISI
SICI code
0167-2738(1993)63-5:<907:RLROL(>2.0.ZU;2-S
Abstract
Room temperature reactions of n-butyllithium with either La2NiO4+y or the electrochemically oxidized La2CuO4+x (x=0.04, 0.08) have been perf ormed. Neutron and X-ray diffraction experiments and magnetic suscepti bility measurements indicate that the process which takes place in the se cases is the reduction of the material by extraction of the interst itial oxygen rather than by the insertion of lithium within the struct ure.