A. Ohsaki et al., FORMATION OF TIN TI ADHESION LAYERS BY COLLIMATED SPUTTERING/, Electronics & communications in Japan. Part 2, Electronics, 78(12), 1995, pp. 59-66
Formation of a TiN/Ti adhesion layer by collimated sputtering for a st
ructured surface with a high aspect ratio was investigated. The bottom
coverage was simulated and the simulated and experimental results wer
e compared. As a result, it was found that the simulated and experimen
tal results were in agreement if the scattering of sputtered particles
by gas was small. Three-dimensional simulation of wall coverage predi
cted a formation of constriction at the top of the contact hole and th
e formation of constriction was confirmed experimentally. The formatio
n of constriction caused the peeling of an adhesion layer when a chemi
cal vapor deposition (CVD) tungsten film was deposited. To avoid the f
ormation of constriction, a tapered contact hole was used. It was foun
d also that the contact resistance and junction leakage characteristic
s were improved by collimation sputtering when an adhesion layer was d
eposited in the contact holes with a high aspect ratio. It was conclud
ed that this technology is advantageous in contact formation in device
s with submicron structures.